HydrogenFluidProperties

Fluid properties for Hydrogen (H2)

Fluid properties for hydrogen are mainly calculated using the Leachman et al. equation of state (Leachman et al., 2009). This formulation uses density and temperature as the primary variables with which to calculate properties such as density, enthalpy and internal energy.

When used with the pressure and temperature interface, which is the case in the Porous Flow module, hydrogen properties are typically calculated by first calculating density iteratively for a given pressure and temperature. This density is then used to calculate the other properties, such as internal energy, directly.

Viscosity is calculated using the formulation presented in Muzny et al. (2013). Thermal conductivity is calculated using the relationship presented in Assael et al. (2011)

Dissolution of hydrogen into water is calculated using Henry's law (IAPWS, 2004).

Properties of hydrogen

Property	value
Molar mass	0.00201588e kg/mol
Critical temperature	33.19 K
Critical pressure	1.315 MPa
Critical density	31.262kg/m $var element = document.getElementById("moose-equation-9a73d1d9-9946-4745-a05b-2ec1d90676ba");katex.render("^3", element, {displayMode:false,throwOnError:false});$
Triple point temperature	13.952 K
Triple point pressure	7.7 kPa

Range of validity

The HydrogenFluidProperties UserObject is valid for:

13.957 K $var element = document.getElementById("moose-equation-fd07fe3a-2081-47ef-a2f9-ca95ad63cca6");katex.render("\\le", element, {displayMode:false,throwOnError:false});$ T $var element = document.getElementById("moose-equation-3ae8e47e-761e-4cbc-be9b-b7d074d96f60");katex.render("\\le", element, {displayMode:false,throwOnError:false});$ 1000 K for p $var element = document.getElementById("moose-equation-08a485f0-96e9-4fab-9437-7bc0386e1ba5");katex.render("\\le", element, {displayMode:false,throwOnError:false});$ 2000 MPa

Input Parameters

execute_onTIMESTEP_ENDThe list of flag(s) indicating when this object should be executed, the available options include NONE, INITIAL, LINEAR, NONLINEAR, POSTCHECK, TIMESTEP_END, TIMESTEP_BEGIN, MULTIAPP_FIXED_POINT_END, MULTIAPP_FIXED_POINT_BEGIN, FINAL, CUSTOM.
Default:TIMESTEP_END
C++ Type:ExecFlagEnum
Options:NONE, INITIAL, LINEAR, NONLINEAR, POSTCHECK, TIMESTEP_END, TIMESTEP_BEGIN, MULTIAPP_FIXED_POINT_END, MULTIAPP_FIXED_POINT_BEGIN, FINAL, CUSTOM
Controllable:No
Description:The list of flag(s) indicating when this object should be executed, the available options include NONE, INITIAL, LINEAR, NONLINEAR, POSTCHECK, TIMESTEP_END, TIMESTEP_BEGIN, MULTIAPP_FIXED_POINT_END, MULTIAPP_FIXED_POINT_BEGIN, FINAL, CUSTOM.
prop_getter_suffixAn optional suffix parameter that can be appended to any attempt to retrieve/get material properties. The suffix will be prepended with a '_' character.
C++ Type:MaterialPropertyName
Controllable:No
Description:An optional suffix parameter that can be appended to any attempt to retrieve/get material properties. The suffix will be prepended with a '_' character.
use_interpolated_stateFalseFor the old and older state use projected material properties interpolated at the quadrature points. To set up projection use the ProjectedStatefulMaterialStorageAction.
Default:False
C++ Type:bool
Controllable:No
Description:For the old and older state use projected material properties interpolated at the quadrature points. To set up projection use the ProjectedStatefulMaterialStorageAction.

Optional Parameters

T_initial_guess400Temperature initial guess for Newton Method variable set conversion
Default:400
C++ Type:double
Controllable:No
Description:Temperature initial guess for Newton Method variable set conversion
p_initial_guess200000Pressure initial guess for Newton Method variable set conversion
Default:200000
C++ Type:double
Controllable:No
Description:Pressure initial guess for Newton Method variable set conversion
tolerance1e-08Tolerance for 2D Newton variable set conversion
Default:1e-08
C++ Type:double
Controllable:No
Description:Tolerance for 2D Newton variable set conversion

Variable Set Conversions Newton Solve Parameters

allow_duplicate_execution_on_initialFalseIn the case where this UserObject is depended upon by an initial condition, allow it to be executed twice during the initial setup (once before the IC and again after mesh adaptivity (if applicable).
Default:False
C++ Type:bool
Controllable:No
Description:In the case where this UserObject is depended upon by an initial condition, allow it to be executed twice during the initial setup (once before the IC and again after mesh adaptivity (if applicable).
allow_imperfect_jacobiansFalsetrue to allow unimplemented property derivative terms to be set to zero for the AD API
Default:False
C++ Type:bool
Controllable:No
Description:true to allow unimplemented property derivative terms to be set to zero for the AD API
control_tagsAdds user-defined labels for accessing object parameters via control logic.
C++ Type:std::vector<std::string>
Controllable:No
Description:Adds user-defined labels for accessing object parameters via control logic.
enableTrueSet the enabled status of the MooseObject.
Default:True
C++ Type:bool
Controllable:Yes
Description:Set the enabled status of the MooseObject.
execution_order_group0Execution order groups are executed in increasing order (e.g., the lowest number is executed first). Note that negative group numbers may be used to execute groups before the default (0) group. Please refer to the user object documentation for ordering of user object execution within a group.
Default:0
C++ Type:int
Controllable:No
Description:Execution order groups are executed in increasing order (e.g., the lowest number is executed first). Note that negative group numbers may be used to execute groups before the default (0) group. Please refer to the user object documentation for ordering of user object execution within a group.
force_postauxFalseForces the UserObject to be executed in POSTAUX
Default:False
C++ Type:bool
Controllable:No
Description:Forces the UserObject to be executed in POSTAUX
force_preauxFalseForces the UserObject to be executed in PREAUX
Default:False
C++ Type:bool
Controllable:No
Description:Forces the UserObject to be executed in PREAUX
force_preicFalseForces the UserObject to be executed in PREIC during initial setup
Default:False
C++ Type:bool
Controllable:No
Description:Forces the UserObject to be executed in PREIC during initial setup
fp_typesingle-phase-fpType of the fluid property object
Default:single-phase-fp
C++ Type:FPType
Controllable:No
Description:Type of the fluid property object
use_displaced_meshFalseWhether or not this object should use the displaced mesh for computation. Note that in the case this is true but no displacements are provided in the Mesh block the undisplaced mesh will still be used.
Default:False
C++ Type:bool
Controllable:No
Description:Whether or not this object should use the displaced mesh for computation. Note that in the case this is true but no displacements are provided in the Mesh block the undisplaced mesh will still be used.

Advanced Parameters

References

Marc J Assael, J-AM Assael, Marcia L Huber, Richard A Perkins, and Yasayuki Takata. Correlation of the thermal conductivity of normal and parahydrogen from the triple point to 1000 k and up to 100 mpa. J. Phys. Chem. Ref. Data, 40(3):033101, 2011.

@article{assael2011,
    author = "Assael, Marc J and Assael, J-AM and Huber, Marcia L and Perkins, Richard A and Takata, Yasayuki",
    title = "Correlation of the Thermal Conductivity of Normal and Parahydrogen from the Triple Point to 1000 K and up to 100 MPa",
    journal = "J. Phys. Chem. Ref. Data",
    volume = "40",
    number = "3",
    pages = "033101",
    year = "2011"
}

IAPWS. Guidelines on the Henry's constant and vapour liquid distribution constant for gases in H$_2$O and D$_2$O at high temperatures. Technical Report, IAPWS, 2004.

@techreport{iapws2004,
    author = "IAPWS",
    title = "{Guidelines on the Henry's constant and vapour liquid distribution constant for gases in H$\_2$O and D$\_2$O at high temperatures}",
    institution = "IAPWS",
    year = "2004"
}

Jacob William Leachman, Richard T Jacobsen, SG Penoncello, and Eric W Lemmon. Fundamental equations of state for parahydrogen, normal hydrogen, and orthohydrogen. J. Phys. Chem. Ref. Data, 38(3):721–748, 2009.

@article{leachman2009,
    author = "Leachman, Jacob William and Jacobsen, Richard T and Penoncello, SG and Lemmon, Eric W",
    title = "Fundamental equations of state for parahydrogen, normal hydrogen, and orthohydrogen",
    journal = "J. Phys. Chem. Ref. Data",
    volume = "38",
    number = "3",
    pages = "721--748",
    year = "2009"
}

Chris D Muzny, Marcia L Huber, and Andrei F Kazakov. Correlation for the viscosity of normal hydrogen obtained from symbolic regression. Journal of Chemical & Engineering Data, 58(4):969–979, 2013.

@article{muzny2013,
    author = "Muzny, Chris D and Huber, Marcia L and Kazakov, Andrei F",
    title = "Correlation for the viscosity of normal hydrogen obtained from symbolic regression",
    journal = "Journal of Chemical \\& Engineering Data",
    volume = "58",
    number = "4",
    pages = "969--979",
    year = "2013"
}

Properties of hydrogen
Range of validity
Input Parameters
References